基于双谱滤波的综合脉冲星时算法研究

毫秒脉冲星的自转频率非常稳定,提供了一种独立的基于遥远自然天体并能持续数百万乃至数十亿年的时间基准,具有稳定性强、运行时间长、服务范围广等特点.为了减弱毫秒脉冲星计时观测中各种高斯噪声对脉冲星时的影响,研究了一种基于双谱滤波的综合脉冲星时构建算法,处理分析了国际脉冲星计时阵(International Pul-sar Timing Array,IPTA)最新发布的4颗毫秒脉冲星(PSR J0437-4715、J0613-0200、J1713+0747和J1909-3744)的观测数据,分析了不同时间尺度综合脉冲星时的稳定性,并与构成国际原子时(International Atomic Time,TAI)的4家授时单位原子钟稳定性进行了比较.结果表明:双谱滤波算法能够较好地抑制观测噪声,提高综合脉冲星时的稳定性.相比于经典加权算法,综合脉冲星时1 yr、10 yr稳定度从7.77×10^-14、8.56×10^-16分别提高到1.50×10^-14、3.50×10^-16,单脉冲星时稳定性的提升也类似.同时发现,综合脉冲星时稳定性在5 yr及以上时间尺度上优于原子钟稳定性,可用于改善当前原子时的长期稳定性.     

Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.     

东昆仑金水口地区格林威尔期超高温麻粒岩

格林威尔期构造事件是了解罗迪尼亚超大陆形成的关键。本文报道了东昆仑造山带东段金水口地区古生代花岗岩中新发现二辉麻粒岩包体,其峰期变质矿物组合为单斜辉石+紫苏辉石+钙长石+石英+磁铁矿。通过锆石U-Pb测年,我们确定二辉麻粒岩样品的峰期变质年龄为995±34Ma,并受到泥盆纪(～417Ma)构造热事件的叠加改造。利用单斜辉石-斜方辉石温压计估算出该区二辉麻粒岩变质峰期温度867～1079℃,压力46～89kbar,属于低压超高温变质的温压范围,可能形成于高地温梯度的岛弧环境。该二辉麻粒岩是首次在东昆仑地区发现的格林威尔期超高温麻粒岩,代表罗迪尼亚超大陆汇聚过程中低压高温变质的产物。该发现对了解东昆仑造山带前寒武纪基底的构造属性和起源有重要意义。     

四川理塘地区二叠—三叠纪硅质岩的地球化学特征及地质意义

甘孜—理塘蛇绿混杂岩带位于西南"三江"东缘,为义敦—理塘弧盆系的重要组成部分,其内部发育大量不同时代不同类型的硅质岩。本次研究在理塘县理觉公路硅质岩夹层泥岩、泥灰岩中发现含有大量的中二叠—晚二叠世牙形石,在查日查东村附近硅质岩中采获中三叠世放射虫。通过对研究区硅质岩岩石学、地球化学特征研究,探讨硅质岩的成因类型及其沉积环境。结果表明,理塘地区硅质岩SiO_2质量分数为66.13%～85.89%, Al_2O_3质量分数为4.69%～7.85%, Al/(Al+Fe+Mn)值介于0.44～0.73之间, U/Th比值为0.10～0.19,δCe值为1.00～1.63,这些特征共同指示其为生物成因硅质岩。Al_2O_3/(Al_2O_3+Fe_2O_3)质量比为0.52～0.79, MnO/TiO_2质量比为0.05～0.27,∑REE为(49.26～165.41)×10~(–6),平均为94.37×10~(–6),(La/Yb)N比值为0.78～2.32,(La/Ce)N比值为0.72～1.26,指示其应形成于大陆边缘环境。理塘地区理觉公路和查日查东村二叠—三叠纪大陆边缘型硅质岩的厘定,不仅丰富了甘孜—理塘蛇绿混杂岩带的物质组成,也为甘孜—理塘洋盆二叠—三叠纪地质演化提供了新的证据。     

Variation behavior of pore-water pressure in warm frozen soil under load and its relation to deformation

Acta Geotechnica - Containing a considerable amount of unfrozen water, frozen soil may produce excess pore-water pressure under external load, especially at temperatures near the thawing point. The...     

A simplified mathematical model for the dam-breach hydrograph for three reservoir geometries following a sudden full dam break

Natural Hazards - The prediction of dam-break water flow at dam site is essential to reduce the potential for loss of damage in the downstream floodplain. In this study, the influence of reservoir...     

地质文化村:科学内涵、建设内容与实施路径

伴随着"生态文明"、"乡村振兴"等国家战略的提出,地质文化村成为拓展服务领域、促进地质工作与社会经济发展融合的重要抓手。本文以地质文化村的六维属性为切入点,探讨了地质文化村的空间载体、建设主题、利益主体、主要功能、行为准则、价值导向等内涵,提出地质文化村是以村域为空间载体,以突出"地质+"或"+地质"文化为主题,以共建共享为发展模式,以多元化功能为特征,以"轻质建设"和"生态旅游"为基准,以人地关系和谐为目标的特色村落。建设重点应以乡村五大振兴为总纲,围绕基础设施和公共服务体系、地质文化产品IP、高效产业及项目、多元人才体系、地质保护措施、文化村管理机构等方面开展;未来应通过强化规划衔接、制定行业标准、开展全国试点、加大资金投入、搭建宣传营销平台和进行系统培训等路径,促进地质文化村的健康持续发展。     

Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.     

基于STIRPAT模型的内蒙古沙漠化地区环境压力分析

实现经济与生态环境的协调发展，已经成为当前治理沙漠化的巨大挑战。如何定量分析人类活动和自然条件对环境的影响，是当前环境经济学界研究的热点问题。以内蒙古自治区71个沙漠化县为研究对象，以1986—2010年为研究区间做面板空间计量实证分析。选取了人口、富裕度、技术水平、风速和降水作为环境基础指标构建STIRPAT模型，从环境压力内在驱动角度定量分析不同的自然因素和人为因素对沙漠化地区环境的综合影响。结果表明：在观测数据范围内，富裕度、技术水平、风速和降水是内蒙古自治区环境压力的主要驱动因素；富裕度每增加1%，环境压力显著增加0.096%；技术水平每变化1%，将引起环境压力相应发生0.084%的变化；风速和降水每变动1%分别使得沙漠地区环境压力显著地增加0.640%和减少0.216%。     

利用综合评分方法评估CMIP5模式对北极海冰的模拟能力

北极海冰冰盖自20世纪以来经历了前所未有的缩减，这使得北极海冰异常对大气环流的反馈作用日益显现。尽管目前的气候模式模拟北极海冰均为减少的趋势，但各模式间仍然存在较大的分散性。为了评估模式对于北极海冰变化及其气候效应的模拟能力，我们将海冰线性趋势和年际异常两者结合起来构造了一种合理的衡量指标。我们还强调巴伦支与卡拉海的重要性，因为前人研究证明此区域海冰异常是近年来影响大尺度大气环流变异的关键因子。根据我们设定的标准，CMIP5模式对海冰的模拟可被归为三种类型。这三组多模式集合平均之间存在巨大的差异，验证了这种分组方法的合理性。此外，我们还进一步探讨了造成模式海冰模拟能力差别的潜在物理因子。结果表明模式所采用的臭氧资料集对海冰模拟能力有显著的影响。